WBJEE - CHEMISTRY
- Number of Questions : 20
- Time : 30 Minutes
- No negative marking.
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Question 1 |
The amount of the heat released when 20 ml 0.5 M NaOH is mixed with 100 ml 0.1 M HCl is x kJ. The heat of neutralization is
A | – 100 x kJ/mol |
B | – 50 x kJ/mol |
C | + 100 x kJ/mol |
D | +50 x kJ/mol |
Question 2 |
If the molecular wt. of Na2S2O3 and I2 are M1 and M2 respectively, then what will be the equivalent wt. of Na2S2O3 and I2 in the following reaction?
A | M1 , M2 |
B | M1 , M2/2 |
C | 2M1 , M2 |
D | M1 , 2M2 |
Question 3 |
An electric current is passed through an aqueous solution of a mixture of alanine (isoelectric point 6.0) glutamic acid (3.2) and arginine (10.7) buffered at pH 6. What is the fate of the three acids?
A | Glutamic acid migrates to anode at pH 6. Arginine is present as a cation and migrates to the cathode. Alanine in a dipolar
ion remains uniformly distributed in solution. |
B | Glutamic acid migrates to cathode and others remain uniformly distributed in solution |
C | All three remain uniformly distributed in solution |
D | All three move to cathode |
Question 4 |
2 gm of metal carbonate is neutralized completely by 100 ml of 0.1 (N) HCl. The equivalent weight of metal carbonate is
A | 50 |
B | 100 |
C | 150 |
D | 200 |
Question 5 |
The electronic transitions from n = 2 to n = 1 will produce shortest wavelength in (where n = principal quantum state)
A | Li+2 |
B | He+ |
C | H |
D | H+ |
Question 6 |
The ease of dehydrohalogenation of alkyl halide with alcoholic KOH is
A | 3° < 2° < 1° |
B | 3° > 2° > 1° |
C | 3° < 2° > 1° |
D | 3° > 2° < 1° |
Question 7 |
In the following electron – dot structure, calculate the formal charge from left to right nitrogen atom
A | – 1, –1, + 1 |
B | – 1, +1, – 1 |
C | + 1, –1, – 1 |
D | + 1, – 1, + 1 |
Question 8 |
The ozone layer forms naturally by
A | the interaction of CFC with oxygen |
B | the interaction of UV radiation with oxygen |
C | the interaction of IR radiation with oxygen |
D | the interaction of oxygen and water vapour |
Question 9 |
The standard reduction potential E° for half reations are
Zn = Zn+2 + Ze E° = +0.76 V
Fe = Fe+2 + Ze E° = + 0.41 V
The EMF of hte cell reaction
Fe+2 + Zn = Zn+2 + Fe is
A | -0.35 V |
B | + 0.35 |
C | +1.17 V |
D | – 1.17 V |
Question 10 |
An element belongs to Group 15 and third period of the periodic table. Its electonic configuration will be
A | 1s22s22p3 |
B | 1s22s22p4 |
C | 1s22s22p63s23p3 |
D | 1s22s22p63s23p2 |
Question 11 |
The energy of an electron in first Bohr orbit of H – atom is – 13.6 eV. The possible energy value of electron in the excited state of Li2+ is
A | – 122.4 eV |
B | – 50.6 eV |
C | – 30.6 eV |
D | 13.6 eV |
Question 12 |
Which one of the following is paramagnetic?
A | N2 |
B | NO |
C | CO |
D | O3 |
Question 13 |
Among the alkenes which one produces tertiary bytyl alcohol on acid hydration
A | CH3 – CH2 – CH = CH2 |
B | CH3 – CH = CH – CH3 |
C | (CH3)2C = CH2 |
D | CH3 – CH = CH2 |
Question 14 |
The representation of the ground state electronic configuration of He by box – diagram as ↑ ↑ is wrong because it violates
A | Hysenberg’s Uncertainty Principle |
B | Bohr’s Quantization Theory of Angular Momenta |
C | Pauli Exclusion Principle |
D | Hund’s Rule |
Question 15 |
A radioactive atom XYM emits two α particles and one β particle successively. The number of neutrons in the nucleus of the product will be
A | X – 4 – Y |
B | X – Y – 5 |
C | X – Y – 3 |
D | X – Y – 6 |
Question 16 |
A | II = III ≈ I |
B | II > III > I |
C | III > II > I |
D | I = III > II |
Question 17 |
The correct order of decreasing acidity of nitrophenols will be
A | m-Nitrophenol > p-Nitrophenol > o-Nitrophenol
|
B | p-Nitrophenol > m- Nitrophenol > o-Nitrophenol |
C | o-Nitrophenol > m- Nitrophenol > p-Nitrophenol |
D | p-Nitrophenol > o-nitrophenol > m-Nitrophenol |
Question 18 |
Which one of the following is not true at room temperature and pressure
A | P4O10 is a white solid |
B | SO2 is a colourless gas |
C | SO3 is a colourless gas |
D | NO2 is a brown gas |
Question 19 |
Two aromatic compounds having formula C7H8O which are easily identifiable by FeCl3 solution test (violet colouration) are
A | o- cresol and benzyl alcohol |
B | m-cresol and p-cresol |
C | o-cresol and p-cresol |
D | methyl phenyl ether and benzyl alcohol |
Question 20 |
Which one of the following has the lowest ionization energy?
A | 1s22s22p6 |
B | 1s22s22p63s1 |
C | 1s22s22p5 |
D | 1s22s22p3 |
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